Adsorption of CO2 and H2O on supported amine sorbents

被引:35
作者
Veneman, Rens [1 ]
Zhao, Wenying [2 ]
Li, Zhenshan [2 ]
Cai, Ningsheng [2 ]
Brilman, Derk W. F. [1 ]
机构
[1] Univ Twente, Fac Sci & Technol, Green Energy Initiat, Sustainable Proc Technol Grp, NL-7500 AE Enschede, Netherlands
[2] Tsinghua Univ, Dept Thermal Engn, Key Lab Thermal Sci & Power Engn MOE, Beijing 100084, Peoples R China
来源
12TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-12 | 2014年 / 63卷
关键词
Adsorption; CO2; H2O; Carbon Capture; supported amines; CO2-INDUCED DEGRADATION; MESOPOROUS SILICA; CARBON-DIOXIDE; ADSORBENTS; CAPTURE; REGENERATION;
D O I
10.1016/j.egypro.2014.11.254
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this work we have evaluated the H2O and CO2 adsorption characteristics of Lewatit VP OC 1065 in view of the potential application of solid sorbents in post combustion CO2 capture. Here we present single component adsorption isotherms for H2O and CO2 as well as co-adsorption experiments. It was concluded that the sorbent material shows a high affinity in the adsorption of H2O. The adsorption of CO2 alone does not prevent the coadsorption of large quantities of water and additional measures are necessary to prevent this from negatively affecting the energy demand of the process. (C) 2014 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-NI) license (http://creativecommons.org/licenses/by-ne-nd/3.0/).
引用
收藏
页码:2336 / 2345
页数:10
相关论文
共 21 条
[1]   Evaluation of a Primary Amine-Functionalized Ion-Exchange Resin for CO2 Capture [J].
Alesi, W. Richard, Jr. ;
Kitchin, John R. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (19) :6907-6915
[2]  
[Anonymous], CHEM ENG J
[3]   The adsorption of H2O and D2O on porous polystyrene adsorbents [J].
Bardina, I. A. ;
Zhukova, O. S. ;
Kovaleva, N. V. ;
Lanin, S. N. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (09) :1525-1531
[4]   Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies [J].
Drage, T. C. ;
Arenillas, A. ;
Smith, K. M. ;
Snape, C. E. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 116 (1-3) :504-512
[5]   Suitability of a Solid Amine Sorbent for CO2 Capture by Pressure Swing Adsorption [J].
Ebner, A. D. ;
Gray, M. L. ;
Chisholm, N. G. ;
Black, Q. T. ;
Mumford, D. D. ;
Nicholson, M. A. ;
Ritter, J. A. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (09) :5634-5641
[6]  
Fisher K.S., 2005, Integrating MEA Regeneration with CO2 Compression and Peaking to Reduce CO2 Capture Costs
[7]   Applications of pore-expanded mesoporous silica.: 2.: Development of a high-capacity, water-tolerant adsorbent for CO2 [J].
Franchi, RS ;
Harlick, PJE ;
Sayari, A .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (21) :8007-8013
[8]   Parametric Study of Solid Amine Sorbents for the Capture of Carbon Dioxide [J].
Gray, M. L. ;
Hoffman, J. S. ;
Hreha, D. C. ;
Fauth, D. J. ;
Hedges, S. W. ;
Champagne, K. J. ;
Pennline, H. W. .
ENERGY & FUELS, 2009, 23 (10) :4840-4844
[9]   Thermal, Oxidative, and CO2-Induced Degradation of Supported Polyethylenimine Adsorbents [J].
Heydari-Gorji, Aliakbar ;
Sayari, Abdelhamid .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (19) :6887-6894
[10]   Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable,of capturing CO2 reversibly [J].
Hicks, Jason C. ;
Drese, Jeffrey H. ;
Fauth, Daniel J. ;
Gray, McMahan L. ;
Qi, Genggeng ;
Jones, Christopher W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (10) :2902-2903