Experimental and theoretical study of 1, 4-naphthoquinone based dye in dye-sensitized solar cells using ZnO photoanode

被引:7
作者
Shinde, Dnyaneshwar [1 ]
Tambade, Popat [1 ]
Pathan, Habib [2 ]
Gadave, Kisan [1 ]
机构
[1] Prof Ramkrishna More Arts Commerce & Sci Coll, Pune, Maharashtra, India
[2] Savitribai Phule Pune Univ, Dept Phys, Pune, Maharashtra, India
关键词
dye-sensitized solar cell; ZnO; naphthoquinone; density functional theory; TDDFT; ORGANIC-DYES; NATURAL DYES; PHOTOVOLTAIC PERFORMANCE; CONVERSION EFFICIENCY; NANOCRYSTALLINE TIO2; PARTICLE-SIZE; ZINC-OXIDE; PHOTOSENSITIZERS; PHOTOELECTRODE; DERIVATIVES;
D O I
10.1515/msp-2017-0088
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A dye-sensitized solar cell (DSSC) was assembled using a dye 4-(3-chloro-1, 4-dioxo-1, 4-dihydronaphthalen-2-ylamino) benzoic acid with ZnO as a photoanode. It was synthesized using 2, 3-dichloro 1, 4-naphthoquinone and p-amino benzoic acid. The spectral features of the dye were analyzed in ethanol using experimental and computational methods. The theoretical investigations revealed that the synthesized dye may act as a sensitizer in DSSCs. The photoelectrochemical performance was tested under direct sunlight using a sandwich type DSSC. The photovoltaic data of the dye adsorbed on ZnO films indicated the power conversion efficiency of 1.07 % under sunlight with a light intensity of 39 mW.cm(-2).
引用
收藏
页码:746 / 754
页数:9
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