Syntheses, structures and luminescence of three new supramolecular complexes containing N-P-acetamidobenzenesulfonyl-glycine acid

被引：16
作者：
Hou, Hongwei [2 ]
Chen, Shuhui [1 ,2 ]
Wang, Liya [1 ]
Ma, Lufang [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 17期
关键词：
N-P-acetamidobenzenesulfonyl-glycine acid; supramolecular structures; fluorescent analysis;
D O I：
10.1080/00958970801975539
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new ligand, N-P-acetamidobenzenesulfonyl-glycine acid (abbreviated as abglyH(2)), and three transition metal complexes [Mn(abglyH)(2)(bipy)(H2O)(2)](n) (1), [Mn(abglyH)(2)(bipy)(2)(H2O)(2)] (2) and [Zn(abglyH)(2)(H2O)(4)] (3) (bipy=4,4'-bipyridine) have been synthesized under mild conditions and characterized by IR, elemental analysis and X-ray diffraction analysis. Compound I exhibits a I-D linear chain, which is further connected to a 3-D supramolecular network through various kinds of hydrogen bonds and p-pi stacking interactions. 2 and 3 are monomeric compounds, and 2 is assembled by intermolecular hydrogen bonds and CH...pi interactions into a 3-D supramolecular network, while 3 is extended into a 2-D supramolecular network through hydrogen bonds. Fluorescent analysis shows that 3 has an emissive maximum at 353nm in the solid state at room temperature.
引用
收藏
页码：2690 / 2702
页数：13
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