The synthesis and crystal structures of di-μ-dichloro-bis{[N,N-dimethylaminobenzyl-C1,N]dipalladium(II)} and of the Cocrystals of {chloro-(triphenylphosphino)-bis[N,N-dimethylaminobenzyl-C1,N]palladium(II) and {trans-bis(triphenylphosphino)-chloro[N,N-dimethylaminobenzyl-C]palladium(II)}

被引：37

作者：

Mentes, A ^{[1
]}

Kemmitt, RDW

Fawcett, J

Russell, DR

机构：

[1] Zonguldak Karaelmas Univ, Fac Arts & Sci, Dept Chem, Zonguldak, Turkey

[2] Univ Leicester, Dept Chem, Inorgan Res Labs, Leicester LE1 7RH, Leics, England

[3] Univ Leicester, Dept Chem, Xray Crystallog Lab, Leicester LE1 7RH, Leics, England

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 693卷 / 1-3期

关键词：

X-ray structure; cyclopalladated; palladium(II); N; N-dimethylbenzylamine; triphenylphosphine; triphenylstibine;

D O I：

10.1016/j.molstruc.2004.03.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The X-ray crystal structures of cyclopalladated complexes are reported. Reaction of {[Pd(dmba)(mu-Cl)](2)}, (1), (dmba = N(CH3)(2)-CH2C6H5) with triphenylphosphine gave crystals containing {chloro-(triphenylphosphino)-bis[N,N-dimethylaminobenzyl-C-1,N] palladium(II)} (2a) and {trans-bis(triphenylphosphino)-chloro-[N,N-dimethylaminozyl-C]palladium(II)} (2b). Complex (1) crystallises in the space group P2(1)/c with a = 7.849(l) Angstrom, b = 15.635(3) Angstrom, c = 8.352(l) Angstrom, beta = 109.29degrees, and D-calc = 1.895 g cm(-3) for Z = 2. Complexes (2a) and (2b) crystallize together in the space group P2(1)/n with a = 9.964(2) Angstrom, b = 34.228(5) Angstrom, c = 18.127(3) Angstrom, beta = 91.91 degrees, and D-calc = 1.439 g cm(-3). (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：241 / 246

页数：6

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