GelatinnZn(CF3SO3)2 Polymer Electrolytes for Electrochromic Devices

被引:22
作者
Alves, Raquel D. [1 ]
Rodrigues, Luisa C. [1 ]
Andrade, Juliana R. [2 ]
Fernandes, Mariana [3 ,4 ]
Pinto, Joana V. [5 ,6 ]
Pereira, Luis [5 ,6 ]
Pawlicka, Agnieszka [2 ]
Martins, Rodrigo [5 ,6 ]
Fortunato, Elvira [5 ,6 ]
Bermudez, Veronica de Zea [3 ,4 ]
Silva, Maria Manuela [1 ]
机构
[1] Univ Minho, Ctr Quim, P-4710057 Braga, Portugal
[2] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13566590 Sao Carlos, SP, Brazil
[3] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001801 Vila Real, Portugal
[4] Univ Tras Os Montes & Alto Douro, CQ VR, P-5001801 Vila Real, Portugal
[5] Univ Nova Lisboa, CENIMAT I3N, Fac Ciencias & Tecnol, Dept Ciencia Mat, P-2829516 Caparica, Portugal
[6] CEMOP UNINOVA, P-2829516 Caparica, Portugal
基金
巴西圣保罗研究基金会;
关键词
Solid polymer electrolytes; Electrochromic devices; Gelatin matrix; Zinc triflate; TRIFLATE;
D O I
10.1002/elan.201300038
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The present work is focused on gelatin-based electrolytes doped with a range of concentration of zinc triflate (Zn(CF3SO3)2). The transparent-thin-film samples have been represented by the notation GelatinnZn(CF3SO3)2, where n represents the zinc triflate salt concentration in the electrolyte membranes from 0.00 wt% to 10.93 wt% . The samples have been characterized by conductivity measurements, thermal analysis, cyclic voltammetry, X-ray diffraction (XRD), polarized optical microscopy (POM) and scanning electron microscopy (SEM). The gelatin-based electrolytes were also tested as ionic conductors in electrochromic devices with the glass/ITO/WO3/gelatin-based electrolyte/CeO2-TiO2/ITO/glass configuration.
引用
收藏
页码:1483 / 1490
页数:8
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