Matrix Synthesis of Water-Soluble Polyaniline in the Presence of Polyelectrolytes

被引：6
作者：
Boeva, Zh. A. [1 ]
Pyshkina, O. A. [1 ]
Lezov, A. A. [2 ]
Polushina, G. E. [2 ]
Lezov, A. V. [2 ]
Sergeyev, V. G. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia
[2] St Petersburg State Univ, Fac Phys, Petrodvorets 198504, Russia
来源：
POLYMER SCIENCE SERIES C | 2010年 / 52卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
PANI; Polymer Science Series; Hydrodynamic Radius; Emeraldine Base; PANI Chain;
D O I：
10.1134/S1811238210010054
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The matrix polymerization of aniline hydrochloride in the presence of polyanions with different chemical structures and molecular masses is studied. Poly(2-acrylamido-2-methyl-1-propanesulfonic acid) and poly(4-styrenesulfonic acid) or its sodium salt are used as polyelectrolyte matrices. It is shown that, if the polymerization of aniline hydrochloride is conducted in the presence of a polyelectrolyte matrix, water-soluble polyelectrolyte complexes in which polyaniline occurs in the form of an emeraldine salt are formed. The mechanism of polymerization is advanced. It is found that the sizes of polyaniline complexes in water are independent of the molecular mass of the polyelectrolyte matrix and its chemical structure.
引用
收藏
页码：35 / 43
页数：9
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