{2,2′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]diphenolato}dioxidomolybdenum(VI)

被引:9
作者
Abbasi, Alireza [1 ]
Sheikhshoaie, Iran [2 ]
Saghaei, Abbas [3 ]
Monadi, Niaz [2 ]
机构
[1] Univ Tehran, Univ Coll Sci, Sch Chem, Tehran 14174, Iran
[2] Shahid Bahonar Univ, Dept Chem, Kerman, Iran
[3] Islamic Azad Univ, Sci & Res Branch, Tehran, Iran
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S160053680802182X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the structure of the title compound, [Mo(C(19)H(20)N(2)O(2))O(2)], the Mo atom exhibits oxidation state + VI and is surrounded by two O atoms and the tetradentate Schiff base ligand 2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]diphenolate in a distorted octahedral configuration. An intramolecular C-H center dot center dot center dot O hydrogen bond between a methylene group and one O atom of the O Mo VI O unit, as well as additional intermolecular hydrogen bonds between neighboring molecules, lead to a weakly bonded inversion-symmetric dimeric structure.
引用
收藏
页码:M1036 / U617
页数:12
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