A Versatile Aqueous Reduction of Bio-Based Carboxylic Acids using Syngas as a Hydrogen Source

被引：24

作者：

Yu, Lei ^{[1
]}

Du, Xian-Long ^{[1
,2
]}

Yuan, Jing ^{[1
]}

Liu, Yong-Mei ^{[1
]}

Cao, Yong ^{[1
]}

He, He-Yong ^{[1
]}

Fan, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 01期

基金：

中国国家自然科学基金;

关键词：

bio-based carboxylic acids; biomass; gold catalysis; hydrogenation; sustainable chemistry; syngas; LIQUID-PHASE HYDROGENATION; GAMMA-VALEROLACTONE; LACTIC-ACID; CATALYTIC CONVERSION; MALEIC-ANHYDRIDE; LEVULINIC ACID; BIOMASS; GOLD; ZIRCONIA; TRANSFORMATION;

D O I：

10.1002/cssc.201200674

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syngas as a versatile hydrogen source: Using readily available and economically favorable syngas as a convenient hydrogen source, an efficient and sustainable aqueous reduction of bio-based carboxylic acids has been achieved over a highly robust catalyst system consisting of gold nanoparticles supported on acid-tolerant single-phase monoclinic zirconia (Au/m-ZrO2). A range of bio-based multifunctional carboxylic acids have been selectively converted into their corresponding lactones or diols in high to excellent yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：42 / 46

页数：5

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