A Versatile Aqueous Reduction of Bio-Based Carboxylic Acids using Syngas as a Hydrogen Source

被引：24
作者：
Yu, Lei [1 ]
Du, Xian-Long [1 ,2 ]
Yuan, Jing [1 ]
Liu, Yong-Mei [1 ]
Cao, Yong [1 ]
He, He-Yong [1 ]
Fan, Kang-Nian [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 01期
基金：
中国国家自然科学基金;
关键词：
bio-based carboxylic acids; biomass; gold catalysis; hydrogenation; sustainable chemistry; syngas; LIQUID-PHASE HYDROGENATION; GAMMA-VALEROLACTONE; LACTIC-ACID; CATALYTIC CONVERSION; MALEIC-ANHYDRIDE; LEVULINIC ACID; BIOMASS; GOLD; ZIRCONIA; TRANSFORMATION;
D O I：
10.1002/cssc.201200674
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Syngas as a versatile hydrogen source: Using readily available and economically favorable syngas as a convenient hydrogen source, an efficient and sustainable aqueous reduction of bio-based carboxylic acids has been achieved over a highly robust catalyst system consisting of gold nanoparticles supported on acid-tolerant single-phase monoclinic zirconia (Au/m-ZrO2). A range of bio-based multifunctional carboxylic acids have been selectively converted into their corresponding lactones or diols in high to excellent yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：42 / 46
页数：5
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