First-principles theory of electrical breakdown in barrier anodic films in contact with an electrolyte

被引：12

作者：

Bordo, V. G. ^{[1
]}

Ebel, T. ^{[1
]}

机构：

[1] Syddansk Univ, Mads Clausen Inst, Ctr Ind Elect, Alsion 2, DK-6400 Sonderborg, Denmark

来源：

ELECTROCHIMICA ACTA | 2020年 / 354卷

关键词：

Electrical breakdown; Breakdown voltage; Injection current; Barrier anodic films; First-principles theory; GROWTH; CONDUCTION; EMISSION; TITANIUM; TUNGSTEN; FIELD;

D O I：

10.1016/j.electacta.2020.136490

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A theory of electrical breakdown in barrier anodic films in contact with an electrolyte which is based on first principles and is capable to consistently explain all empirical relations is developed. The corresponding empirical coefficients are expressed in terms of the microscopic parameters. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：9

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