Unique conformation and packing structure of p-sulfonatocalix[5]arene induced by 1,2-bis(pyridinium)ethane compounds

被引:25
作者
Guo, Dong-Sheng [1 ]
Zhang, Heng-Yi [1 ]
Li, Chun-Ju [1 ]
Liu, Yu [1 ]
机构
[1] Nankai Univ, Dept Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1039/b603569h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the presence of 1,2-bis(4,4'-dipyridinium) ethane, p-sulfonatocalix[ 5] arene (C5AS) adopts an unseen partial-cone conformation to form back-to-back dimers, whereas C5AS crystallizes in face-to-face dimers to form a wavy layer, rather than the expected bilayer, arrangement upon complexation with 1,2-bis( pyridinium) ethane.
引用
收藏
页码:2592 / 2594
页数:3
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