Microwave-Assisted Synthesis of Alkyl Thiocyanates

被引：9

作者：

Bound, D. James ^{[1
]}

Bettadaiah, B. K. ^{[1
]}

Srinivas, P. ^{[1
]}

机构：

[1] Cent Food Technol Res Inst, Plantat Prod Spices & Flavour Technol Dept, Council Sci & Ind Res, Mysore 570020, Karnataka, India

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 08期

关键词：

Allyl; benzyl; halides; isothiocyanates; microwave; selectivity; t-alkyl; thiocyanates; zinc thiocyanate; NUCLEOPHILIC-SUBSTITUTION; ZINC SALTS; HALIDES;

D O I：

10.1080/00397911.2011.622848

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Microwave irradiation accelerated the reaction of t-alkyl, allyl, and benzyl halides with Zn(SCN)(2) to afford thiocyanates in excellent yields and high selectivity with the formation of isothiocyanates only in minor proportions. Because thiocyanates are stable intermediates to thiols, the method also affords facile access to corresponding thiols.

引用

页码：1138 / 1144

页数：7

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