Rapid electrochemical synthesis of HKUST-1 on indium tin oxide

被引：32

作者：

Jiang, Li-Long ^{[2
]}

Zeng, Xiangzhou ^{[1
]}

Li, Mengkai ^{[1
]}

Wang, Man-Qing ^{[1
]}

Su, Tong-Yu ^{[1
]}

Tian, Xiao-Chun ^{[3
]}

Tang, Jing ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Chem & Chem Engn, Key Lab Anal & Detect Technol Food Safety, Minist Educ, Fuzhou 350108, Fujian Province, Peoples R China

[2] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Coll Chem & Chem Engn, Fuzhou 350108, Fujian Province, Peoples R China

[3] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian Province, Peoples R China

来源：

RSC ADVANCES | 2017年 / 7卷 / 15期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; REDUCTION;

D O I：

10.1039/c6ra26646k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We synthesized a HKUST-1 metal-organic framework (MOF) on indium tin oxide (ITO) using an electrodeposited Cu film. The electrodeposited Cu/ITO was used as a source of Cu ions, which were linked with benzene-1,3,5-tricarboxylic acid on the ITO surface to form HKUST-1. Synthesized HKUST-1/ITO was characterized by X-ray diffraction (XRD), Raman spectroscopy and scanning electron microscopy (SEM), which showed that the morphology of the HKUST-1 framework was nearly octahedral. Our results also revealed that the growth of HKUST-1 depended on the potential and synthesis time used. This method can be applied to fabricate ordered patterns of HKUST-1 on ITO substrates, offering a new way to grow MOFs on many other kinds of conductive substrates.

引用

页码：9316 / 9320

页数：5

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