Poly(dibenzylidene)tetrathiapentalene :: in situ ESR and conductivity measurements

被引：0

作者：

Divisia-Blohorn, B ^{[1
]}

Genoud, F

Müller, H

Salhi, F

机构：

[1] CEA, Dept Rech Fondamentale Matiere Condensee, UJF,CNRS, UMR 5819,Lab Electrochim Mol & Struct Interfaces, F-38054 Grenoble 9, France

[2] CEA, Dept Rech Fondamentale Matiere Condensee, UJF,CNRS, UMR 5819,Lab Phys Metaux Synthet, F-38054 Grenoble, France

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

in situ electrochemical spectroscopy; electron spin resonance; conductivity; tetrathiapentalenes;

D O I：

10.1016/S0379-6779(98)00832-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The results of spectroelectrochemical ESR studies as well as of in situ conductivity measurements performed on poly[(2,5-dibenzylidene)-1,3,4,6-tetrathiapentalene] (polyDBTTP 1) are presented. The polymer comprises polaron/bipolaron systems corresponding to the presence of three redox systems. The relative electrical resistivity strongly depends on the applied potential and correlates well with the spin density. A partially oxidized state 2 bearing one positive charge per monomer unit accounts for the conducting properties of the material.

引用

页码：390 / 391

页数：2