Diquaternary (CH3)2(C2H5)N+(CH2)nN+(C2H5)(CH3)2 and (C2H5)2-(CH3)N+(CH2)nN+(CH3)(C2H5)2 ions with n=4-6 as structuredirecting agents in zeolite synthesis

被引:0
作者
Han, B [1 ]
Shin, CH
Nam, IS
Hong, SB
机构
[1] Hanbat Natl Univ, Div Chem Engn, Taejon 305719, South Korea
[2] Chungbuk Natl Univ, Dept Chem Engn, Chungbuk 361763, South Korea
[3] Pohang Univ Sci & Technol, Dept Chem Engn, Sch Environm Engn, Pohang 790784, South Korea
来源
MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B | 2005年 / 158卷
关键词
STRUCTURE-DIRECTING AGENTS; CATALYTIC-PROPERTIES; CATIONS; N; N'; N'-HEXAETHYLPENTANEDIAMMONIUM; N=3-10; ZSM-57; SUZ-4; P1;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of flexible, linear diquaternary alkylarmmonium ions (CH3)(2)(C2H5)N+(CH2)N+-(C2H5)(CH3)(2) (Me4Et2-diquat-n) and (C2H5)(2)(CH3)N+(CH2)(n)N+(CH3)(C2H5)(2) (Et4Me2-diquat-n) with n = 4-6 as struture-directing agents in zeolite syntheses is described. Among the ammonium ions studied here, the Et4Me2-diqtiat-4 and Et4Me2-diquat-6 ions were found to be new structure-directing agents for the crystallization of MCM-47 and SSZ-16, respectively.
引用
收藏
页码:183 / 190
页数:8
相关论文
共 17 条
[1]   MCM-47: A highly crystalline silicate composed of hydrogen-bonded ferrierite layers [J].
Burton, A ;
Accardi, RJ ;
Lobo, RF ;
Falcioni, M ;
Deem, MW .
CHEMISTRY OF MATERIALS, 2000, 12 (10) :2936-2942
[2]   Zeolite synthesis using flexible diquaternary alkylammonium ions (CnH2n+1)2HN+(CH2)5N+H(CnH2n+1)2 with n=1-5 as structure-directing agents [J].
Han, B ;
Lee, SH ;
Shin, CH ;
Cox, PA ;
Hong, SB .
CHEMISTRY OF MATERIALS, 2005, 17 (03) :477-486
[3]  
Han B, UNPUB
[4]   Synthesis, structure solution, characterization, and catalytic properties of TNU-10: A high-silica zeolite with the STI topology [J].
Hong, SB ;
Lear, EG ;
Wright, PA ;
Zhou, WZ ;
Cox, PA ;
Shin, CH ;
Park, JH ;
Nam, IS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) :5817-5826
[5]   Synthesis of zeolite ZSM-57 and its catalytic evaluation for the 1-butene skeletal isomerization and n-octane cracking [J].
Lee, SH ;
Lee, DK ;
Shin, CH ;
Paik, WC ;
Lee, WM ;
Hong, SB .
JOURNAL OF CATALYSIS, 2000, 196 (01) :158-166
[6]   Reinvestigation into the synthesis of zeolites using diquaternary alkylammonium ions (CH3)3N+(CH2)nN+(CH3)3 with n=3-10 as structure-directing agents [J].
Lee, SH ;
Shin, CH ;
Yang, DK ;
Ahn, SD ;
Nam, IS ;
Hong, SB .
MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 68 (1-3) :97-104
[7]   Zeolite synthesis in the presence of flexible diquaternary alkylammonium ions (C2H5)3N+(CH2)nN+(C2H5)3 with n=3-10 as structure-directing agents [J].
Lee, SH ;
Shin, CH ;
Choi, GJ ;
Park, TJ ;
Nam, IS ;
Han, B ;
Hong, SB .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :237-249
[8]   Synthesis of zeolite MCM-22 using N,N,N,N′,N′,N′-hexamethyl-1,5-pentanediaminium and alkali metal cations as structure-directing agents [J].
Lee, SH ;
Shin, CH ;
Hong, SB .
CHEMISTRY LETTERS, 2003, 32 (06) :542-543
[9]   Synthesis, characterization, and catalytic properties of zeolites IM-5 and NU-88 [J].
Lee, SH ;
Lee, DK ;
Shin, CH ;
Park, YK ;
Wright, PA ;
Lee, WM ;
Hong, SB .
JOURNAL OF CATALYSIS, 2003, 215 (01) :151-170
[10]  
Lin-Vien D., 1991, HDB INFRARED RAMAN C