Influence of additives on the performance of photografted jute yarn with 3-(trimethoxysilyl)propylmethacrylate

被引:16
作者
Hassan, MM
Islam, MR
Khan, MA
机构
[1] Bangladesh Atom Energy Commiss, Inst Nucl Sci & Technol, Radiat & Polymer Chem Lab, Dhaka, Bangladesh
[2] Bangladesh Natl Univ, MC Coll, Dept Chem, Sylhet, Bangladesh
[3] Jahangirnagar Univ, Dept Chem, Dhaka, Bangladesh
关键词
natural fiber; jute; photocuring; UV radiation; silane;
D O I
10.1080/10236660500397878
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
3-(Trimethoxysilyl)propylmethacrylate (silane) solutions of different concentrations in methanol (MeOH) along with the photoinitiator Irgacure 907 were grafted onto jute yarn. Jute yarn grafted with 30% silane under UV radiation for 30 min showed the highest polymer loading (PL) value, 26.2%, with enhanced tensile strength (TS) (259%) and elongation-at-break (Eb) (337%) as compared to untreated yarn. The silanized and virgin jute yarns were characterized by X-ray photoelectron spectroscopy. To attain better performance of jute yarn, the additives (1%) urea, polyvinylpyrrolidone, urethane acrylate, and urethane diacrylate (UDAc) were used in 30% silane. Of the additives used, urea significantly influenced the PL (29%), TS (300%), and Eb (360%) values of the treated jute yarns. Water uptake and the degradation studies were also performed.
引用
收藏
页码:179 / 194
页数:16
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