Formation of octapod MnO nanoparticles with enhanced magnetic properties through kinetically-controlled thermal decomposition of polynuclear manganese complexes

被引：33

作者：

Douglas, Fraser J. ^{[1
]}

MacLaren, Donald A. ^{[2
]}

Tuna, Floriana ^{[3
]}

Holmes, William M. ^{[4
]}

Berry, Catherine C. ^{[5
]}

Murrie, Mark ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Glasgow, Sch Phys & Astron, SUPA, Glasgow G12 8QQ, Lanark, Scotland

[3] Univ Manchester, Natl EPR Ctr, Manchester M13 9PL, Lancs, England

[4] Univ Glasgow, Inst Neurosci & Psychol, GEMRIC, Glasgow G12 8QQ, Lanark, Scotland

[5] Univ Glasgow, Ctr Cell Engn, CMVLS, Glasgow G12 8QQ, Lanark, Scotland

来源：

NANOSCALE | 2014年 / 6卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

IRON-OXIDE NANOPARTICLES; CONTRAST AGENT; LIVER MRI; SIZE; NANOCRYSTALS; RELAXIVITY; NANORODS; MN3O4; WATER; SHAPE;

D O I：

10.1039/c3nr04832b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polynuclear manganese complexes are used as precursors for the synthesis of manganese oxide nanoparticles (MnO NPs). Altering the thermal decomposition conditions can shift the nanoparticle product from spherical, thermodynamically-driven NPs to unusual, kinetically-controlled octapod structures. The resulting increased surface area profoundly alters the NP's surface-dependent magnetism and may have applications in nanomedicine.

引用

页码：172 / 176

页数：5

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