Identifying electrocatalytic activity and mechanism of Ce1/3NbO3 perovskite for nitrogen reduction to ammonia at ambient conditions

被引：66

作者：

Hu, Xuemin ^{[1
]}

Sun, Yuntong ^{[1
]}

Guo, Shiying ^{[2
]}

Sun, Jingwen ^{[1
]}

Fu, Yongsheng ^{[1
]}

Chen, Sheng ^{[1
]}

Zhang, Shengli ^{[2
]}

Zhu, Junwu ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Minist Educ, Nanjing 210094, Peoples R China

[2] Nanjing Univ Sci & Technol, Coll Mat Sci & Engn, Inst Optoelect & Nanomat, Nanjing 210094, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2021年 / 280卷

关键词：

Ce1/3NbO3; Nitrogen reduction reaction; Electrocatalyst; Reaction mechanism; DFT calculation; CATALYTIC-REDUCTION; MOFE PROTEIN; OXYGEN; PERFORMANCE; FIXATION; IRON; NH3;

D O I：

10.1016/j.apcatb.2020.119419

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, a novel Ce1/3NbO3 perovskite is proposed as an efficient electrocatalyst to catalyze the nitrogen reduction reaction (NRR) at ambient conditions. Density functional theory calculations are firstly used to predict the potential N-2 activation ability of Ce1/3NbO3, and then, the Ce1/3NbO3 with a flower-like porous structure is prepared by a hydrothermal process and post calcination. Electrochemical tests reveal that such catalyst achieves a high NRR performance with the Faradaic efficiency of 6.87% and NH3 yield of 10.34 mu g h(-1) cm(-2) at - 0.8 V vs RHE in 0.1 M Na2SO4, keeping up with many electrocatalysts reported recently. The mechanistic studies disclose that Nb atom is favorable as the efficient active site for NRR by the distal pathway, and Ce atom synergistically enhances the charge transfer during the NRR process. Our work provides an important reference to the rational design of the promising electrocatalysts for NRR.

引用

页数：8

共 73 条

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