Triton-B catalyzed, efficient, one-pot synthesis of carbamate esters from alcoholic tosylates

被引：32

作者：

Chaturvedi, Devdutt ^{[1
]}

Ray, Suprabhat ^{[1
]}

机构：

[1] Cent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India

来源：

MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 04期

关键词：

alcoholic tosylates; triton-B; carbon dioxide; N-alkyl/aryl carbamates;

D O I：

10.1007/s00706-005-0452-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel process for the one-step chemoselective conversion of a variety of alcoholic tosylates into carbamates serving as protected an-fines was developed using benzyltrimethylammonium hydroxide (Triton-B) in the presence of gaseous carbon dioxide. Thus carbamate esters of different amines were prepared in very good to excellent yields.

引用

页码：459 / 463

页数：5

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