Triton-B catalyzed, efficient, one-pot synthesis of carbamate esters from alcoholic tosylates

被引：32
作者：
Chaturvedi, Devdutt [1 ]
Ray, Suprabhat [1 ]
机构：
[1] Cent Drug Res Inst, Med & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India
来源：
MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 04期
关键词：
alcoholic tosylates; triton-B; carbon dioxide; N-alkyl/aryl carbamates;
D O I：
10.1007/s00706-005-0452-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel process for the one-step chemoselective conversion of a variety of alcoholic tosylates into carbamates serving as protected an-fines was developed using benzyltrimethylammonium hydroxide (Triton-B) in the presence of gaseous carbon dioxide. Thus carbamate esters of different amines were prepared in very good to excellent yields.
引用
收藏
页码：459 / 463
页数：5
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