Magnetic nanoparticle-supported guanidine as a highly recyclable and efficient nanocatalyst for the cyanosilylation of carbonyl compounds

被引：68

作者：

Atashkar, Bahareh ^{[1
]}

Rostami, Amin ^{[1
]}

Tahmasbi, Bahman ^{[1
]}

机构：

[1] Univ Kurdistan, Fac Sci, Dept Chem, Sanandaj 6617715175, Iran

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 08期

关键词：

SOLVENT-FREE CYANOSILYLATION; CYANOHYDRIN TRIMETHYLSILYL ETHERS; ENANTIOSELECTIVE CYANOSILYLATION; RECOVERABLE CATALYSTS; ALDEHYDES; ACID; KETONES; CYANIDE; NANOCOMPOSITES; PERSPECTIVE;

D O I：

10.1039/c3cy00190c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Guanidine supported onto magnetic Fe3O4 nanoparticles was prepared and evaluated as a recoverable interphase nanocatalyst for the cyanosilylation of carbonyl compounds in good to high yields using trimethylsilylcyanide (TMSCN) in CH2Cl2 at room temperature. This simple experimental and product isolation procedure combined with easy recovery and high reusability (up to 20) of the catalyst are expected to contribute to the development of clean strategy for the preparation of silylated cyanohydrins.

引用

页码：2140 / 2146

页数：7

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