Iron-Catalyzed Hydrogenation Reactions

被引：34

作者：

Guo, Na ^{[1
]}

Zhu, Shoufei ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, State Key Lab & Inst Elemento Organ Chem, Tianjin 300071, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 07期

基金：

中国国家自然科学基金;

关键词：

iron catalyst; hydrogenation; unsaturated organic compound; PHASE ORGANOMETALLIC KINETICS; COOPERATIVE TRANSITION-METAL; NEUTRAL-LIGAND COMPLEXES; ASYMMETRIC HYDROGENATION; BIS(IMINO)PYRIDINE IRON; ENANTIOSELECTIVE HYDROGENATION; HOMOGENEOUS HYDROGENATION; SELECTIVE HYDROGENATION; EFFICIENT HYDROGENATION; HIGHLY EFFICIENT;

D O I：

10.6023/cjoc201502032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transition-metal-catalyzed hydrogenation of unsaturated organic compounds including alkenes, alkynes, aldehydes, ketones, and imines, is one of the most important organic transformations for both academic researches and industrial applications. The most popular catalysts for hydrogenation reactions are based on precious metals, such as rhodium, ruthenium, iridium, and palladium. The exhausting resource, the increasing high price, and the toxicity of the precious metals restrict their future applications. Iron is the most abundant transition metal in the earth crust and therefore the cheapest one with excellent environmental benign characters, is considered as an ideal replacement of the precious metal catalysts for hydrogenation reactions. This review paper introduced the newest achievements in the study of iron-catalyzed hydrogenation reactions in both homogenous and heterogeneous systems.

引用

页码：1383 / 1398

页数：16

共 101 条

[1] Asymmetric homogeneous hydrogenations at scale [J].

Ager, David J. ;

de Vries, Andre H. M. ;

de Vries, Johannes G. .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (08) :3340-3380

[2]

[Anonymous], FE H COMPLEXES CATAL

[3]

[Anonymous], HYDROGENATION HETERO

[4]

[Anonymous], 2007, The Handbook of Homogeneous Hydrogenation

[5]

[Anonymous], MODERN ALCHEMY REPLA

[6]

[Anonymous], IRON CATALYSIS ORGAN

[7] Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation [J].

Archer, Andrew M. ;

Bouwkamp, Marco W. ;

Cortez, Maria-Patricia ;

Lobkovsky, Emil ;

Chirik, Paul J. .

ORGANOMETALLICS, 2006, 25 (18) :4269-4278

[8] Low-valent α-diimine iron complexes for catalytic olefin hydrogenation [J].

Bart, SC ;

Hawrelak, EJ ;

Lobkovsky, E ;

Chirik, PJ .

ORGANOMETALLICS, 2005, 24 (23) :5518-5527

[9] Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation [J].

Bart, SC ;

Lobkovsky, E ;

Chirik, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) :13794-13807

[10] Neutral-ligand complexes of bis(imino)pyridine iron: Synthesis, structure, and spectroscopy [J].

Bart, Suzanne C. ;

Lobkovsky, Emil ;

Bill, Eckhard ;

Wieghardt, Karl ;

Chirik, Paul J. .

INORGANIC CHEMISTRY, 2007, 46 (17) :7055-7063

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