Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions

被引：31

作者：

Ushakov, E. N. ^{[1
,2
]}

Gromov, S. P. ^{[2
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[2] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2015年 / 84卷 / 08期

基金：

俄罗斯基础研究基金会; 俄罗斯科学基金会;

关键词：

ETHER STYRYL DYES; ASSEMBLED COORDINATION CAGE; ANION-CAPPED COMPLEXES; TEMPLATING PHOTODIMERIZATION; GAMMA-CYCLODEXTRIN; REGIOSELECTIVE PHOTODIMERIZATION; PSEUDODIMERIC COMPLEX; CINNAMIC-ACIDS; SOLID-STATE; WATER;

D O I：

10.1070/RCR4514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review deals with the methods of supramolecular chemistry used for controlling the efficiency and stereoselectivity of intermolecular [2 + 2] photocycloaddition of olefins and other unsaturated compounds in homogeneous solutions. The best-studied methods are self-assembly through cation macrocycle interactions, complexation with molecular templates through hydrogen bonding, and confinement of the reactants in supramolecular containers. The possibilities of using anionic templates and combined supramolecular approaches are discussed. The bibliography includes 107 references.

引用

页码：787 / 802

页数：16

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