A note on the stoichiometric mechanism for ligand replacement reactions of square-planar complexes of platinum(II)

被引：0
作者：
Banerjea, D. [1 ]
机构：
[1] Univ Calcutta, Chem, Kolkata 700073, W Bengal, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2015年 / 92卷 / 08期
关键词：
SUBSTITUTION-REACTIONS; AQUEOUS-SOLUTION; ION; ACTIVATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Based on available evidence in literature, particularly insensitivity of the rate on the overall charge on the complex, ligand replacement reactions of square-planar complexes of platinum(II) are best regarded as interchange (1) process in which bond formation and bond dissociation make comparable contributions in generating the transition state. But for isoelectronic gold(III) the reactions are associative (A).
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页码：1319 / 1320
页数：2
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