Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs

被引：13

作者：

Lieffrig, Julien ^{[1
]}

Jeannin, Olivier ^{[1
]}

Shin, Kyoung-Soon ^{[1
]}

Auban-Senzier, Pascale ^{[2
]}

Fourmigue, Marc ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, CNRS, UMR 6226, F-35042 Rennes, France

[2] Univ Paris 11, Phys Solides Lab, CNRS, UMR 8502, F-91405 Orsay, France

来源：

CRYSTALS | 2012年 / 2卷 / 02期

关键词：

charge-transfer salts; halogen bonding; tetrathiafulvalene; crystal structure; iodine; magnetism; RADICAL-CATION SALTS; TETRATHIAFULVALENE; COMPLEXES; DONOR; CL; ANION; BR;

D O I：

10.3390/cryst2020327

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Oxidation of 3,4-ethylenedithio-3'-iodo-tetrathiafulvalene (EDT-TTF-I) and 3,4-ethylenedithio-3',4'-diiodo-tetrathiafulvalene (EDT-TTF-I2) with DDQ afforded two different salts formulated as (EDT-TTF-I)(DDQ) and (EDT-TTF-I-2)(2)(DDQ)center dot(CH3CN), both characterized with a full charge transfer to the DDQ acceptor moiety and by short and linear halogen bonding interactions between the iodine atom as halogen bond donor, and the carbonyl oxygen or the nitrile nitrogen atoms of reduced DDQ.

引用

页码：327 / 337

页数：11

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