Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs

被引：13

作者：

Lieffrig, Julien ^{[1
]}

Jeannin, Olivier ^{[1
]}

Shin, Kyoung-Soon ^{[1
]}

Auban-Senzier, Pascale ^{[2
]}

Fourmigue, Marc ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, CNRS, UMR 6226, F-35042 Rennes, France

[2] Univ Paris 11, Phys Solides Lab, CNRS, UMR 8502, F-91405 Orsay, France

来源：

CRYSTALS | 2012年 / 2卷 / 02期

关键词：

charge-transfer salts; halogen bonding; tetrathiafulvalene; crystal structure; iodine; magnetism; RADICAL-CATION SALTS; TETRATHIAFULVALENE; COMPLEXES; DONOR; CL; ANION; BR;

D O I：

10.3390/cryst2020327

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Oxidation of 3,4-ethylenedithio-3'-iodo-tetrathiafulvalene (EDT-TTF-I) and 3,4-ethylenedithio-3',4'-diiodo-tetrathiafulvalene (EDT-TTF-I2) with DDQ afforded two different salts formulated as (EDT-TTF-I)(DDQ) and (EDT-TTF-I-2)(2)(DDQ)center dot(CH3CN), both characterized with a full charge transfer to the DDQ acceptor moiety and by short and linear halogen bonding interactions between the iodine atom as halogen bond donor, and the carbonyl oxygen or the nitrile nitrogen atoms of reduced DDQ.

引用

页码：327 / 337

页数：11

共 50 条

[1] Activating both Halogen and Chalcogen Bonding Interactions in Cation Radical Salts of Iodinated Tetrathiafulavalene Derivatives
Beau, Maxime
Jeannin, Olivier
Lee, Sunhee
Barriere, Frederic
Fourmigu, Marc
Jeon, Ie-Rang
CHEMPLUSCHEM, 2020, 85 (09): : 2136 - 2142
[2] On the role of charge transfer in halogen bonding
Rezac, Jan
de la Lande, Aurelien
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (01) : 791 - 803
[3] Role of Charge Transfer in Halogen Bonding
Inscoe, Brandon
Rathnayake, Hemali
Mo, Yirong
JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 125 (14): : 2944 - 2953
[4] Charge density studies on halogen bonding interactions
Bhadbhade, Mohan M.
Gonnade, Rajesh G.
Munshi, Parthapratim
Row, Tayur N. Guru
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : C568 - C568
[5] Impact of Hydrogen and Halogen Bonding Interactions on the Packing and Ionicity of Charge-Transfer Cocrystals
Goud, N. Rajesh
Matzger, Adam J.
CRYSTAL GROWTH & DESIGN, 2017, 17 (01) : 328 - 336
[6] Atomic dipole polarization in charge-transfer complexes with halogen bonding
Bartashevich, E. V.
Tsirelson, V. G.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (07) : 2530 - 2538
[7] Halogen-halogen interactions and halogen bonding in thiacalixarene systems
Yamada, Manabu
Kanazawa, Ryo
Hamada, Fumio
CRYSTENGCOMM, 2014, 16 (13): : 2605 - 2614
[8] Charge-Assisted Hydrogen Bonds and Halogen-Halogen Interactions in Organic Salts: Benzylammonium Benzoates and Pentafluorobenzoates
Christer B. Aakeröy
Alicia M. Beatty
Keith R. Lorimer
Structural Chemistry, 1999, 10 : 229 - 242
[9] Charge-assisted hydrogen bonds and halogen-halogen interactions in organic salts:: Benzylammonium benzoates and pentafluorobenzoates
Aakeröy, CB
Beatty, AM
Lorimer, KR
STRUCTURAL CHEMISTRY, 1999, 10 (03) : 229 - 242
[10] TRANSIENT CHARGE-TRANSFER INTERACTIONS IN ALKYL HALIDE -- HALOGEN SYSTEMS
STRONG, RL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 174 (SEP): : 43 - 43

← 1 2 3 4 5 →