Tuning the structural topologies of two luminescent metal-organic frameworks through altering auxiliary ligand

被引：40

作者：

Yang, Gui-bin ^{[1
]}

Sun, Zhen-Hai ^{[1
]}

机构：

[1] Harbin Univ, Sch Sci, Harbin 150086, Heilongjiang, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 29卷

关键词：

Hydrothermal synthesis; Metal-organic framework; Interpenetration; Topology; COORDINATION POLYMERS; PHYSICAL-PROPERTIES;

D O I：

10.1016/j.inoche.2012.12.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal-organic frameworks, [Zn-2(FA)(2)(bix)(2)](n) center dot 3nH(2)O (1) and [Zn(FA)(bib)](n) (2), (H(2)FA = fumaric acid, bix = 4,4'-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazolyl)butane), have been synthesized by combining the fumaric acid and flexible imidazole-based ligands with Zn(II) salts under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 is a 4-fold interpenetrated unc topological net, and 2 is a 5-fold interpenetrated dia topological net. Moreover, the luminescent properties of the two compounds were also investigated in the solid state at room temperature. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.

引用

页码：94 / 96

页数：3

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