1-D to 3-D lanthanide coordination polymers constructed from 5-aminoisophthalic acid and oxalic acid

被引：21

作者：

Jin, Hong-Guang

Yan, Yuan-Zhao

Li, Jing

Gu, Zhi-Gang

Chen, Jin-Hao

Liu, Yi-Ting

Zheng, Zhi-Peng

Zhan, Qing-Guang

Cai, Yue-Peng ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 23卷

基金：

中国国家自然科学基金;

关键词：

Lanthanide metal organic frameworks; Mixed-carboxylates; Fluorescence; SUPRAMOLECULAR ISOMERISM; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; COMPLEXES; CHANNELS;

D O I：

10.1016/j.inoche.2012.05.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three lanthanide metal organic frameworks (MOFs) with mixed carboxylates of 5-aminoisophthalic acid (H(2)AIP) and oxalic acid (H2OX), namely [Yb(AIP)(OX)(0.5)(H2O)(3)](n)center dot H2O (1), [Tb(HAIP)(OX)(H2O)](n) (2), and {[Er(AIP)(OX)(0.5)(H2O)]center dot H2O}(n) (3) were obtained by hydrothermal reactions and characterized by elemental analysis, IR spectra and thermogravimetric analysis, as well as single crystal X-ray diffraction. These frameworks exhibit three typical structural features: complex 1 possesses one-dimensional ladder-like chain, 2 has two-dimensional layer, and 3 is three-dimensional framework. Moreover, the fluorescent property of 2 is also investigated. (C) 2012 Published by Elsevier B.V.

引用

页码：25 / 30

页数：6

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