An Iodine-Promoted, Mild and Efficient Method for the Synthesis of Phenols from Arylboronic Acids

被引：102

作者：

Gogoi, Ankur ^{[1
]}

Bora, Utpal ^{[1
]}

机构：

[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India

来源：

SYNLETT | 2012年 / 07期

关键词：

arylboronic acid; phenol; hydroxylation; hydrogen peroxide; iodine; PALLADIUM-CATALYZED HYDROXYLATION; ARYL HALIDES; HYDROGEN-PEROXIDE; ROOM-TEMPERATURE; MOLECULAR-IODINE; BORONIC ESTERS; ETHERS; OXYGEN; CONVERSION; HYDROXIDE;

D O I：

10.1055/s-0031-1290654

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and efficient methodology for the ipso-hydroxylation of arylboronic acids to phenols has been developed using aqueous hydrogen peroxide as oxidizing agent and molecular iodine as catalyst. The reactions were performed at room temperature in short reaction time under metal-, ligand- and base-free conditions.

引用

页码：1079 / 1081

页数：3

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