Thermotropic poly(azomethine-urethane)s with non linear optical properties: Synthesis and characterization

被引:7
作者
Ali, Ilias [1 ,2 ]
Al-Zahrani, S. M. [1 ,2 ]
Dolui, S. K. [3 ]
机构
[1] King Saud Univ, Dept Chem Engn, Riyadh 11421, Saudi Arabia
[2] King Saud Univ, SPRC, Riyadh 11421, Saudi Arabia
[3] Tezpur Univ, Dept Chem Sci, Napaam, India
关键词
POLYURETHANES;
D O I
10.1134/S1560090412060012
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two series of the thermotropic main chain poly(azomethine-urethane)s were synthesized by the polyaddition of azadiol, 1,8-octandiol with methylene bis(phenyl isocyanate) (MDI) and tolylene 2,4-diisocyanate (TDI) respectively. The mesomorphic properties and phase transition temperature of the polymers were characterized by differential scanning calorimetry and hot stage polarizing microscopy. These polymers showed nematic messophase. The non linear optical (NLO) activity of the polymers was also investigated.
引用
收藏
页码:342 / 348
页数:7
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