Electron-Beam Mapping of Vibrational Modes with Nanometer Spatial Resolution

被引:86
作者
Dwyer, C. [1 ]
Aoki, T. [2 ]
Rez, P. [1 ]
Chang, S. L. Y. [2 ]
Lovejoy, T. C. [3 ]
Krivanek, O. L. [1 ,3 ]
机构
[1] Arizona State Univ, Dept Phys, Tempe, AZ 85287 USA
[2] Arizona State Univ, LeRoy Eyring Ctr Solid State Sci, Tempe, AZ 85287 USA
[3] Nion Co, 11511 NE 118th St, Kirkland, WA 98034 USA
关键词
SPECTROSCOPY; MICROSCOPE;
D O I
10.1103/PhysRevLett.117.256101
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We demonstrate that a focused beam of high-energy electrons can be used to map the vibrational modes of a material with a spatial resolution of the order of one nanometer. Our demonstration is performed on boron nitride, a polar dielectric which gives rise to both localized and delocalized electron-vibrational scattering, either of which can be selected in our off-axial experimental geometry. Our experimental results are well supported by our calculations, and should reconcile current controversy regarding the spatial resolution achievable in vibrational mapping with focused electron beams.
引用
收藏
页数:5
相关论文
共 22 条
[1]  
Chen C, 2014, NAT COMMUN, V5, DOI [10.1038/ncomms4312, 10.1038/ncomms4357]
[2]   Localization of high-energy electron scattering from atomic vibrations [J].
Dwyer, C. .
PHYSICAL REVIEW B, 2014, 89 (05)
[3]   Prospects for Vibrational-Mode EELS with High Spatial Resolution [J].
Egerton, R. F. .
MICROSCOPY AND MICROANALYSIS, 2014, 20 (03) :658-663
[4]  
Egerton R.F., 1996, ELECT ENERGY LOSS SP
[5]   Probing low-energy hyperbolic polaritons in van der Waals crystals with an electron microscope [J].
Govyadinov, Alexander A. ;
Konecna, Andrea ;
Chuvilin, Andrey ;
Velez, Saul ;
Dolado, Irene ;
Nikitin, Alexey Y. ;
Lopatin, Sergei ;
Casanova, Felix ;
Hueso, Luis E. ;
Aizpurua, Javier ;
Hillenbrand, Rainer .
NATURE COMMUNICATIONS, 2017, 8
[6]   Stimulated excitation electron microscopy and spectroscopy [J].
Howie, A. .
ULTRAMICROSCOPY, 2015, 151 :116-121
[7]  
Howie A., ULTRAMICROS IN PRESS
[8]   Ab initio calculation of the lattice dynamics and phase diagram of boron nitride [J].
Kern, G ;
Kresse, G ;
Hafner, J .
PHYSICAL REVIEW B, 1999, 59 (13) :8551-8559
[9]   Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set [J].
Kresse, G ;
Furthmuller, J .
PHYSICAL REVIEW B, 1996, 54 (16) :11169-11186
[10]   From ultrasoft pseudopotentials to the projector augmented-wave method [J].
Kresse, G ;
Joubert, D .
PHYSICAL REVIEW B, 1999, 59 (03) :1758-1775