Structural studies of thermal- and light-induced transitions in iron(II) spin-crossover complexes

被引：16

作者：

Thompson, AL ^{[1
]}

Money, VA ^{[1
]}

Goeta, AE ^{[1
]}

Howard, JAK ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

来源：

COMPTES RENDUS CHIMIE | 2005年 / 8卷 / 9-10期

关键词：

spin-crossover; spin transition; molecular magnetism; crystal structure; LIESST; variable temperature diffraction studies; iron(II) complexes; coordination polymers; polymorphism; allosterism;

D O I：

10.1016/j.crci.2004.09.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Since the spin-crossover (SCO) effect was first discovered, considerable efforts have been made to study compounds that exhibit this phenomenon. Herein we present a selection of our most exciting results from structural studies carried out on some of the fascinating iron(II) SCO compounds we have investigated over the past few years. We discuss a range of compounds from mononuclear to bimetallic polymeric complexes.

引用

页码：1365 / 1373

页数：9

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