Advances in biomass transformation to 5-hydroxymethylfurfural and mechanistic aspects

被引：105

作者：

Dutta, Saikat ^{[1
]}

De, Sudipta ^{[2
]}

Saha, Basudeb ^{[2
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Delhi, Dept Chem, Catalysis Lab, Delhi 110007, India

来源：

BIOMASS & BIOENERGY | 2013年 / 55卷

关键词：

Biomass; Cellulose; Lignocellulosics; Dehydration mechanism; Sustainable chemistry; MICROWAVE-ASSISTED CONVERSION; ACID-CATALYZED HYDROLYSIS; IONIC-LIQUID; D-FRUCTOSE; LIGNOCELLULOSIC BIOMASS; ETHANOL-PRODUCTION; LEVULINIC ACID; CELLULOSE; DEHYDRATION; GLUCOSE;

D O I：

10.1016/j.biombioe.2013.02.008

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Biomass-derived 5-hydroxymethylfurfural (HMF) has been emerged as a key platform chemical for the production of fine chemicals and liquid fuels. The direct transformation of cellulose and lignocellulosic biomass into HMF in ionic liquids and organic solvents is most desired in terms of process economics and sustainability. The focus of this review is purely on the HMF production from cellulose and lignocelluloses and mechanistic aspects of HMF formation in order to bridge the gap in understanding the factors responsible for selective conversion and selection of catalyst. Additionally, present review is devoted exclusively to the latest developments, namely microwave-assisted degradation of cellulose to HMF, application of solid acid and ionic-liquid catalysis to address their effectiveness for HMF production. Approaches for the cellulose transformation into HMF are especially emphasized in order to explore newer avenues of biomass as renewable feedstock for energy and chemicals. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：355 / 369

页数：15

共 104 条

[1] 5-hydroxymethyl-2-furfural modifies intracellular sickle haemoglobin and inhibits sickling of red blood cells [J].

Abdulmalik, O ;

Safo, MK ;

Chen, QK ;

Yang, JS ;

Brugnara, C ;

Ohene-Frempong, K ;

Abraham, DJ ;

Asakura, T .

BRITISH JOURNAL OF HAEMATOLOGY, 2005, 128 (04) :552-561

[2] Solid-acid and ionic-liquid catalyzed one-pot transformation of biorenewable substrates into a platform chemical and a promising biofuel [J].

Alam, Md. Imteyaz ;

De, Sudipta ;

Dutta, Saikat ;

Saha, Basudeb .

RSC ADVANCES, 2012, 2 (17) :6890-6896

[3] Mechanism of the dehydration of D-fructose to 5-hydroxymethylfurfural in dimethyl sulfoxide at 150 °C: an NMR study [J].

Amarasekara, Ananda S. ;

Williams, LaToya D. ;

Ebede, Chidinma C. .

CARBOHYDRATE RESEARCH, 2008, 343 (18) :3021-3024

[4]

[Anonymous], 2005, European Technology Platform on Nanomedicine, Nanotechnology for Health: Vision paper and basis for a strategic research agenda for nanomedicine

[5]

Arredondo-Vega Bertha O., 1995, Cytobios, V83, P201

[6] Catalytic conversion of biomass using solvents derived from lignin [J].