Stability of garnet-type Li ion conductors: An overview

被引：92

作者：

Duan, Huanan ^{[1
]}

Zheng, Hongpeng ^{[1
]}

Zhou, Ying ^{[1
]}

Xu, Biyi ^{[1
]}

Liu, Hezhou ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Key Lab Met Matrix Composites, Sch Mat Sci & Engn, Shanghai 200240, Peoples R China

来源：

SOLID STATE IONICS | 2018年 / 318卷

关键词：

SOLID-ELECTROLYTE; DOPED LI7LA3ZR2O12; INTERFACE MODIFICATION; CHEMICAL-STABILITY; OXIDE ELECTROLYTES; CUBIC LI7LA3ZR2O12; LITHIUM BATTERY; 1ST-PRINCIPLES; CONDUCTIVITY; FABRICATION;

D O I：

10.1016/j.ssi.2017.09.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Garnet-type lithium ion conductor is a promising candidate of solid electrolyte on the way towards all-solid-state lithium ion batteries. This short review presents the latest efforts on the stability of lithium garnet against ambient air, lithium metal, cathodes, and liquid electrolytes. The discussion on the air stability includes the reaction mechanisms as well as the effects of material properties and environmental parameters. The interface stability with Li metal and cathode materials covers both thermodynamic computation and experimental results. The Strategies to reduce the garnet/Li interfacial impedance and to subsequently suppress the Li dendrite formation are highlighted. The last section on "hybrid electrolyte" discusses the stability of lithium garnets in liquid electrolytes, namely aprotic and aqueous electrolytes.

引用

页码：45 / 53

页数：9

共 74 条

[1] Investigating the Dendritic Growth during Full Cell Cycling of Garnet Electrolyte in Direct Contact with Li Metal [J].

Aguesse, Frederic ;

Manalastas, William ;

Buannic, Lucienne ;

Lopez del Amo, Juan Miguel ;

Singh, Gurpreet ;

Llordes, Anna ;

Kilner, John .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (04) :3808-3816

[2] Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction [J].

Bachman, John Christopher ;

Muy, Sokseiha ;

Grimaud, Alexis ;

Chang, Hao-Hsun ;

Pour, Nir ;

Lux, Simon F. ;

Paschos, Odysseas ;

Maglia, Filippo ;

Lupart, Saskia ;

Lamp, Peter ;

Giordano, Livia ;

Shao-Horn, Yang .

CHEMICAL REVIEWS, 2016, 116 (01) :140-162

[3] Contact between Garnet-Type Solid Electrolyte and Lithium Metal Anode: Influence on Charge Transfer Resistance and Short Circuit Prevention [J].

Basappa, Rajendra Hongahally ;

Ito, Tomoko ;

Yamada, Hirotoshi .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (04) :A666-A671

[4]

Busche MR, 2016, NAT CHEM, V8, P426, DOI [10.1038/NCHEM.2470, 10.1038/nchem.2470]

[5] Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte [J].

Cheng, Eric Jianfeng ;

Sharafi, Asma ;

Sakamoto, Jeff .

ELECTROCHIMICA ACTA, 2017, 223 :85-91

[6] Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li7La3Zr2O12 Solid Electrolytes [J].

Cheng, Lei ;

Wu, Cheng Hao ;

Jarry, Angelique ;

Chen, Wei ;

Ye, Yifan ;

Zhu, Junfa ;

Kostecki, Robert ;

Persson, Kristin ;

Guo, Jinghua ;

Salmeron, Miguel ;

Chen, Guoying ;

Doeff, Marca .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (32) :17649-17655

[7] Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes [J].

Cheng, Lei ;

Chen, Wei ;

Kunz, Martin ;

Persson, Kristin ;

Tamura, Nobumichi ;

Chen, Guoying ;

Doeff, Marca .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (03) :2073-2081

[8] The origin of high electrolyte-electrode interfacial resistances in lithium cells containing garnet type solid electrolytes [J].

Cheng, Lei ;

Crumlin, Ethan J. ;

Chen, Wei ;

Qiao, Ruimin ;

Hou, Huaming ;

Lux, Simon Franz ;

Zorba, Vassilia ;

Russo, Richard ;

Kostecki, Robert ;

Liu, Zhi ;

Persson, Kristin ;

Yang, Wanli ;

Cabana, Jordi ;

Richardson, Thomas ;

Chen, Guoying ;

Doeff, Marca .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (34) :18294-18300

[9] All solid state lithium batteries based on lamellar garnet-type ceramic electrolytes [J].

Du, Fuming ;

Zhao, Ning ;

Li, Yiqiu ;

Chen, Cheng ;

Liu, Ziwei ;

Guo, Xiangxin .

JOURNAL OF POWER SOURCES, 2015, 300 :24-28

[10] Toward garnet electrolyte-based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface [J].

Fu, Kun ;

Gong, Yunhui ;

Liu, Boyang ;

Zhu, Yizhou ;

Xu, Shaomao ;

Yao, Yonggang ;

Luo, Wei ;

Wang, Chengwei ;

Lacey, Steven D. ;

Dai, Jiaqi ;

Chen, Yanan ;

Mo, Yifei ;

Wachsman, Eric ;

Hu, Liangbing .

SCIENCE ADVANCES, 2017, 3 (04)

← 1 2 3 4 5 6 7 8 →