Tris(tricarbonyl(triphenylphosphine)ruthenium

被引：3

作者：

Bell, ZR ^{[1
]}

Laye, RH ^{[1
]}

Ward, MD ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802004932

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ru(CO)(3)(PPh3)](3), has three ruthenium centres, each in an octahedral environment with distortion from ideal geometry. The compound contains the characteristic triangular Ru-3 core, with the phosphorus ligands each occupying an equatorial position at one end of an Ru-Ru vector.

引用

页码：M165 / M166

页数：2

共 4 条

[1] CLUSTER CHEMISTRY .55. STEREOCHEMISTRY OF GROUP 15 LIGAND-SUBSTITUTED DERIVATIVES OF RU3(CO)12, O53(CO)12 .A. X-RAY STRUCTURES OF 6 COMPLEXES M3(CO)11(L) (M = RU, L = PPH(OME)2, P(OCH2CF3)3, P(OCH2)3CET AND ASPH3 - M = OS, L = PPH3 AND PPH(OME)2) [J].