Enhanced Visible and Ultraviolet Light-Induced Gas-Phase Photocatalytic Activity of TiO2Thin Films Modified by Increased Amount of Acetylacetone in Precursor Solution for Spray Pyrolysis

TiO(2)thin films, modified by acetylacetone (AcacH) in solution, were deposited on glass substrate by ultrasonic spray pyrolysis and tested for photocatalytic activity in a multi-section continuous flow reactor by degradation of acetone and acetaldehyde under ultraviolet and visible light. The increase in molar ratio of AcacH in respect of titanium (IV) isopropoxide (TTIP) from 1:5 to 1:8 modified the electronic structure of the films, favoring enhanced photocatalytic activity. The photocatalytic activity was enhanced approximately twofold on the film with molar ratio 1:8 under both irradiations; the film completely oxidized 10 ppm of acetone and acetaldehyde. The photocatalytic efficacy of TiO(2)films in oxidation of air pollutants was three times higher compared to the industrial glass Pilkington Activ(TM). Moreover, all the synthesized films indicate antibacterial efficiency againstE. coliof over 99% under ultraviolet. TiO(2)film, with TTIP:AcacH molar ratio 1:8 having great possibility for its commercial use as a material for indoor air purification.