Palladium-catalyzed desulfitative addition of sodium sulfinates with α,β-unsaturated carbonyl compounds

被引：37

作者：

Chen, Wen ^{[1
]}

Zhou, Xianya ^{[1
]}

Xiao, Fuhong ^{[1
]}

Luo, Jiaying ^{[1
]}

Deng, Guo-Jun ^{[1
]}

机构：

[1] Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Coll Chem, Xiangtan 411105, Peoples R China

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 33期

基金：

中国国家自然科学基金;

关键词：

Addition; Desulfination; Palladium; Sulfinic acids; BOND-FORMING REACTIONS; HECK-TYPE REACTION; DIRECT ESI-MS; CONJUGATE ADDITION; ARYLBORONIC ACIDS; ARYL KETONES; ASYMMETRIC 1,4-ADDITION; COUPLING REACTION; BENZOIC-ACIDS; RHODIUM;

D O I：

10.1016/j.tetlet.2012.06.026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed desulfitative conjugate addition of sodium sulfinates with alpha,beta-unsaturated carbonyl compounds is described. The reaction showed very good selectivity and tolerated a wide range of functionalities under an atmosphere of argon. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：4347 / 4350

页数：4

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