Palladium-catalyzed desulfitative addition of sodium sulfinates with α,β-unsaturated carbonyl compounds

被引：37
|
作者：
Chen, Wen [1 ]
Zhou, Xianya [1 ]
Xiao, Fuhong [1 ]
Luo, Jiaying [1 ]
Deng, Guo-Jun [1 ]
机构：
[1] Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Coll Chem, Xiangtan 411105, Peoples R China
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 33期
基金：
中国国家自然科学基金;
关键词：
Addition; Desulfination; Palladium; Sulfinic acids; BOND-FORMING REACTIONS; HECK-TYPE REACTION; DIRECT ESI-MS; CONJUGATE ADDITION; ARYLBORONIC ACIDS; ARYL KETONES; ASYMMETRIC 1,4-ADDITION; COUPLING REACTION; BENZOIC-ACIDS; RHODIUM;
D O I：
10.1016/j.tetlet.2012.06.026
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed desulfitative conjugate addition of sodium sulfinates with alpha,beta-unsaturated carbonyl compounds is described. The reaction showed very good selectivity and tolerated a wide range of functionalities under an atmosphere of argon. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4347 / 4350
页数：4
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