A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules

被引：15

作者：

Wei, Rong-Jia ^{[1
]}

Shiga, Takuya ^{[1
]}

Newton, Graham N. ^{[2
]}

Robinson, David ^{[2
]}

Takeda, Sadamu ^{[3
]}

Oshio, Hiroki ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England

[3] Hokkaido Univ, Dept Chem, Fac Sci, Kita 10,Nishi 8, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 23期

基金：

日本学术振兴会;

关键词：

METAL CHARGE-TRANSFER; ELECTRON-TRANSFER; SINGLE-MOLECULE; CHAIN;

D O I：

10.1021/acs.inorgchem.6b02306

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self assembly. The complex exhibited remarkable multi functionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solidstate H-2 NMR spectra.

引用

页码：12114 / 12117

页数：4

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