A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules

被引：15
|
作者：
Wei, Rong-Jia [1 ]
Shiga, Takuya [1 ]
Newton, Graham N. [2 ]
Robinson, David [2 ]
Takeda, Sadamu [3 ]
Oshio, Hiroki [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
[2] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England
[3] Hokkaido Univ, Dept Chem, Fac Sci, Kita 10,Nishi 8, Sapporo, Hokkaido 0600810, Japan
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 23期
基金：
日本学术振兴会;
关键词：
METAL CHARGE-TRANSFER; ELECTRON-TRANSFER; SINGLE-MOLECULE; CHAIN;
D O I：
10.1021/acs.inorgchem.6b02306
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self assembly. The complex exhibited remarkable multi functionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solidstate H-2 NMR spectra.
引用
收藏
页码：12114 / 12117
页数：4
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