Cellulose nanocrystals from pineapple leaf, a new approach for the reuse of this agro-waste

Pineapple leaf (PL) is an annually renewable agricultural residue, available in abundance, which is used very rarely and is of limited value at present. Therefore, this agro-waste deserves to be better and/or properly used. The aim of this study was to explore PL as a source of raw material for the production of cellulose nanocrystals (CN). The CN were extracted by acid hydrolysis at 45 degrees C for 5,30 or 60 min, using 20 mL of H2SO4 (9.17 M) for each gram of material. The resulting CN were characterized by crystallinity index, FTIR, morphology (shape and size) and thermal stability. Among the hydrolysis conditions carried out, the best extraction time was 30 min. At this extraction time, the CN presented a needle-shaped nature, high thermal stability (225 degrees C), high crystallinity (73%), an average length of 249.7 +/- 51.5 nm and a diameter of 4.45 +/- 1.41 nm, giving an aspect ratio (LID) of around 60. Therefore, CN obtained from PL has great potential as reinforcement in the manufacture of nanocomposites. The production of CN from this underutilized agro-waste has commercial application potential that can add value to the pineapple cultivation, generate extra income for farmers and also help in agribusiness diversification. In addition, the reuse of these residues allows a significant reduction in both the volume of waste accumulated in the environment and in the extraction of raw materials. (C) 2013 Elsevier B.V. All rights reserved.