The first use of chiral oxazoline ligands in the highly enantioselective diethylzinc addition to diphenylphosphinoyl imines

被引：37
作者：
Zhang, XM
Lin, WQ
Gong, LZ [1 ]
Mi, AQ
Cui, X
Jiang, YZ
Choi, MCK
Chan, ASC
机构：
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
[2] Hong Kong Polytech Univ, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 08期
基金：
中国国家自然科学基金;
关键词：
diethylzinc addition; imines; oxazolines;
D O I：
10.1016/S0040-4039(02)00014-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of chiral oxazolines, which had been conveniently prepared from commercially available (1S, 2S)-2-amino-1-phenylpropane-1,3-diol, was applied in the diethylzine addition to diphenylphosphinoyl imines to give high yields of 68-84% and excellent e.e values of 90-93%. (C) 2002 Published by Elsevier Science Ltd.
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页码：1535 / 1537
页数：3
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