Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

被引：45

作者：

Bhattacharya, Saurav ^{[1
]}

Ayass, Wassim W. ^{[1
]}

Taffa, Dereje H. ^{[2
]}

Schneemann, Andreas ^{[3
]}

Semrau, A. Lisa ^{[3
]}

Wannapaiboon, Suttipong ^{[3
]}

Altmann, Philipp J. ^{[3
]}

Poethig, Alexander ^{[3
]}

Nisar, Talha ^{[4
]}

Balster, Torsten ^{[4
]}

Burtch, Nicholas C. ^{[5
]}

Wagner, Veit ^{[4
]}

Fischer, Roland A. ^{[3
]}

Wark, Michael ^{[2
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Dept Life Sci & Chem, Campus Ring 1, D-28759 Bremen, Germany

[2] Carl von Ossietzky Univ Oldenburg, Inst Chem, D-26129 Oldenburg, Germany

[3] Tech Univ Munich, Lichtenbergstr 4, D-85748 Garching, Germany

[4] Jacobs Univ, Dept Phys & Earth Sci, Campus Ring 1, D-28759 Bremen, Germany

[5] Sandia Natl Labs, Livermore, CA 94551 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 08期

关键词：

CROSS-COUPLING REACTION; SUZUKI-MIYAURA; COORDINATION POLYMER; PALLADIUM; ADSORPTION; CHEMISTRY; CATALYST; OXIDATION; OXYGEN; ROUTE;

D O I：

10.1021/jacs.8b13397

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)(8)H-6](8-) decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

引用

页码：3385 / 3389

页数：5

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