New triterpenoid glycosides from Thalictrum minus L.: 11.: Structure of thalicoside H1

被引:3
作者
Trofimova, NN
Gromova, AS
Lutsky, VI
Semenov, AA
Avilov, SA
Li, D
Owen, NL
机构
[1] Russian Acad Sci, Siberian Branch, Irkutsk Inst Chem, Irkutsk 664033, Russia
[2] Russian Acad Sci, Far Eastern Branch, Pacific Inst Bioorgan Chem, Vladivostok 690022, Russia
[3] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
关键词
Thalictrum; Ranunculaceae; triterpenoid glycosides; cycloartane; 1D and 2D NMR spectroscopy; FAB mass spectrometry;
D O I
10.1007/BF02496188
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
From the terrestrial part of Thalictrum minus L. (Ranunculaceae) a novel triterpenoid diglycoside was isolated. The genin of this glycoside is a new cycloartane triterpenoid. The structure of the glycoside was established on the basis of 1D and 2D NMR spectroscopy and FAB mass spectrometry as 22S,25-epoxy-3-O-beta-D-galactopyranosyl-29-O-beta-D-glucopyranosyl- 9 beta,19-cyclo-20S-lanostane-3 beta,16 beta,24S,29-tetrol.
引用
收藏
页码:596 / 599
页数:4
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