ε-caprolactam:: New by-product free synthesis routes

被引：160
作者：
Dahlhoff, G [1 ]
Niederer, JPM [1 ]
Hoelderich, WF [1 ]
机构：
[1] Univ Technol, Rhein Westfal TH Aachen, Dept Chem Technol & Heterogeneous Catalysis, Aachen, Germany
来源：
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2001年 / 43卷 / 04期
关键词：
epsilon-caprolactam; state-of-the-art routes; butadiene-based routes; heterogeneously catalyzed routes; nylon recycling;
D O I：
10.1081/CR-120001808
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The production of the nylon precursor e-caprolactam via the Beckmann rearrangement is one of the large industrial processes worldwide. In this work, the state-of-the-art processes are summarized and the two main pathways For new production capacities (the butadiene-based and especially the heterogeneously catalyzed routes starting from benzene/cyclohexanone oxime) are described. Additionally, the new recycling processes to recover caprolactam from waste carpets and some new approaches are described.
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收藏
页码：381 / 441
页数：61
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