Luminescent properties of red phosphors K2Ba(MoO4)2:Eu3+ for white light emitting diodes

被引:15
作者
Li Zhaomei [1 ]
Zhong Yingjuan [1 ]
Gao Shaokang [1 ]
机构
[1] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
关键词
K2Ba(MoO4)(2):Eu3+; red phosphor; luminescence; charge compensations; rare earths; PHOTOLUMINESCENCE; SM3+;
D O I
10.1016/S1002-0721(12)60166-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
K2Ba(MoO4)(2):Eu3+ phosphors were synthesized by solid-state reaction. The emission and excitation spectra of K2Ba(MoO4)(2):Eu3+ phosphors exhibited that the phosphors could be effectively excited by near ultraviolet (394 nm) and blue (465 nm) light, and emitted red light at 616 nm. The influence of Eu3+ concentration, sintering temperature and charge compensators (K+, Na+ or Li+) on the emission intensity were investigated. The results indicated that concentration quenching of Eu3+ was not observed within 30 mol.% Eu3+, 600 degrees C was a suitable sintering temperature for preparation of K2Ba(MoO4)(2):Eu3+ phosphors, and K+ ions gave the best improvement to enhance the emission intensity. The CIE chromaticity coordinates of K2Ba(MoO4)(2):0.05Eu(3+) phosphor were calculated to be (0.68, 0.32), and color purity was 97.4%.
引用
收藏
页码:990 / 994
页数:5
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