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Luminescent properties of red phosphors K2Ba(MoO4)2:Eu3+ for white light emitting diodes
被引:15
作者:
Li Zhaomei
[1
]
Zhong Yingjuan
[1
]
Gao Shaokang
[1
]
机构:
[1] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
关键词:
K2Ba(MoO4)(2):Eu3+;
red phosphor;
luminescence;
charge compensations;
rare earths;
PHOTOLUMINESCENCE;
SM3+;
D O I:
10.1016/S1002-0721(12)60166-5
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
K2Ba(MoO4)(2):Eu3+ phosphors were synthesized by solid-state reaction. The emission and excitation spectra of K2Ba(MoO4)(2):Eu3+ phosphors exhibited that the phosphors could be effectively excited by near ultraviolet (394 nm) and blue (465 nm) light, and emitted red light at 616 nm. The influence of Eu3+ concentration, sintering temperature and charge compensators (K+, Na+ or Li+) on the emission intensity were investigated. The results indicated that concentration quenching of Eu3+ was not observed within 30 mol.% Eu3+, 600 degrees C was a suitable sintering temperature for preparation of K2Ba(MoO4)(2):Eu3+ phosphors, and K+ ions gave the best improvement to enhance the emission intensity. The CIE chromaticity coordinates of K2Ba(MoO4)(2):0.05Eu(3+) phosphor were calculated to be (0.68, 0.32), and color purity was 97.4%.
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页码:990 / 994
页数:5
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