Bis(silylenyl)- and Bis(germylenyl)-Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)-Cobalt Complexes

被引：146

作者：

Wang, Wenyuan ^{[1
]}

Inoue, Shigeyoshi ^{[1
]}

Enthaler, Stephan ^{[1
]}

Driess, Matthias ^{[1
]}

机构：

[1] Tech Univ Berlin, Dept Chem Met Organ & Inorgan Mat, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 25期

关键词：

cycloadditions; germanium; pyridines; silicon; transition-metal complex; COORDINATION CHEMISTRY; SILYLENE; REACTIVITY; PYRIDINES; COMPOUND; BOND; CYCLOTRIMERIZATION; LIGANDS; ALKYNES; MILD;

D O I：

10.1002/anie.201202175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Strong bite: The two respective Si II and Ge II centers in ferrocene-containing bis(silylene) and bis(germylene) ligands 1 can serve as excellent donors, as shown in the formation of Co complexes 2 (see scheme, Cp=· 5-cyclopentadienyl). Unexpectedly, only the bis(silylene)-Co complex 2 is a precatalyst for the [2+2+2] cycloaddition of phenylacetylene and MeCN, possibly because of a stronger coordination of the Ge II donor centers to Co. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6167 / 6171

页数：5

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