Raman spectroscopic study of the uranyl tellurite mineral moctezumite PbUO2(TeO3)2

被引：28

作者：

Frost, Ray L. ^{[1
]}

Cejka, Jiri ^{[2
]}

Dickfos, Marilla J.

机构：

[1] Queensland Univ Technol, Inorgan Mat Res Program, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia

[2] Natl Museum, CZ-11579 Prague 1, Czech Republic

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2009年 / 40卷 / 01期

关键词：

moctezumite; uranyl tellurite; Raman spectroscopy; infrared spectroscopy; U-O bond length; MOLECULAR-STRUCTURE; CRYSTAL-CHEMISTRY; GIBBS ENERGY; U6+ MINERALS; URANIUM; SHEET; SCHMITTERITE; PARAGENESIS; HIERARCHY; PHASES;

D O I：

10.1002/jrs.2069

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The uranyl tellurite mineral moctezumite, Pb(UO2)(TeO3)(2), was studied by Raman spectroscopy and complemented with infrared spectroscopy. The presence of the stretching and bending vibrations of uranyl (UO2)(2+) and tellurite (TeO3)(2-) ions was inferred, and the observed bands were assigned to uranyl and tellurite units vibrations. U-O bond lengths calculated from the spectra with two empirical relations are close to those inferred from the X-ray single-crystal structure of moctezumite. Copyright (c) 2008 John Wiley & Sons, Ltd.

引用

页码：38 / 41

页数：4

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