Amphiphilic supramolecular A(B)2A quasi-triblock copolymers

被引:9
作者
Mansfeld, Ulrich [1 ,2 ,3 ]
Winter, Andreas [1 ,2 ,3 ]
Hager, Martin D. [1 ,2 ,3 ]
Festag, Grit [1 ,2 ]
Hoeppener, Stephanie [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ,3 ]
机构
[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany
[2] Univ Jena, Jena Ctr Soft Matter, D-07743 Jena, Germany
[3] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands
关键词
TERPYRIDINE METAL-COMPLEXES; MAIN-CHAIN; BUILDING-BLOCKS; POLYMERS; METALLOPOLYMERS; ASSEMBLIES; EXCHANGE; MELT; ION;
D O I
10.1039/c3py00216k
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The efficient synthesis of a responsive amphiphilic supramolecular triblock copolymer A(B)(2)A is described, where the blocks are held together by self-complementary hydrogen bonding at the homojunction (B-B) and by heteroleptic metal complexes at the heterojunction (A-B). The supramolecular copolymer was prepared in a minimum of steps by using heterotelechelic building blocks with orthogonal binding sites polymerized in one step.
引用
收藏
页码:3177 / 3181
页数:5
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