Amphiphilic supramolecular A(B)2A quasi-triblock copolymers

被引：9

作者：

Mansfeld, Ulrich ^{[1
,2
,3
]}

Winter, Andreas ^{[1
,2
,3
]}

Hager, Martin D. ^{[1
,2
,3
]}

Festag, Grit ^{[1
,2
]}

Hoeppener, Stephanie ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany

[2] Univ Jena, Jena Ctr Soft Matter, D-07743 Jena, Germany

[3] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 11期

关键词：

TERPYRIDINE METAL-COMPLEXES; MAIN-CHAIN; BUILDING-BLOCKS; POLYMERS; METALLOPOLYMERS; ASSEMBLIES; EXCHANGE; MELT; ION;

D O I：

10.1039/c3py00216k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The efficient synthesis of a responsive amphiphilic supramolecular triblock copolymer A(B)(2)A is described, where the blocks are held together by self-complementary hydrogen bonding at the homojunction (B-B) and by heteroleptic metal complexes at the heterojunction (A-B). The supramolecular copolymer was prepared in a minimum of steps by using heterotelechelic building blocks with orthogonal binding sites polymerized in one step.

引用

页码：3177 / 3181

页数：5

共 50 条

[1] Phase behavior of the melt of polystyrene-poly(ethylene oxide) metallo-supramolecular diblock copolymer with bulky counterions [J].

Al-Hussein, M ;

de Jeu, WH ;

Lohmeijer, BGG ;

Schubert, US .

MACROMOLECULES, 2005, 38 (07) :2832-2836

[2] Melt morphology of polystyrene-poly(ethylene oxide) metallo-supramolecular diblock copolymer [J].

Al-Hussein, M ;

Lohmeijer, BGG ;

Schubert, US ;

de Jeu, WH .

MACROMOLECULES, 2003, 36 (25) :9281-9284

[3] Supramolecular polymers and networks with hydrogen bonds in the main- and side-chain [J].

Binder, Wolfgang H. ;

Zirbs, Ronald .

HYDROGEN BONDED POLYMERS, 2007, 207 (01) :1-78

[4] Supramolecular polymers [J].

Brunsveld, L ;

Folmer, BJB ;

Meijer, EW ;

Sijbesma, RP .

CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097

[5] New insights into nickel(II), iron(II), and cobalt(II) bis-complex-based metallo-supramolecular polymers [J].

Chiper, Manuela ;

Meier, Michael A. R. ;

Kranenburg, Johannes M. ;

Schubert, Ulrich S. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (07) :679-689

[6] Toward Main Chain Metallo-Terpyridyl Supramolecular Polymers: "The Metal Does the Trick" [J].

Chiper, Manuela ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (08) :565-578

[7] Construction and Degradation of Polyrotaxane Multilayers [J].

Dam, Henk H. ;

Caruso, Frank .

ADVANCED MATERIALS, 2011, 23 (27) :3026-+

[8] Materials science - Supramolecular polymers [J].

de Greef, Tom F. A. ;

Meijer, E. W. .

NATURE, 2008, 453 (7192) :171-173

[9] Supramolecular Polymerization [J].

De Greef, Tom F. A. ;

Smulders, Maarten M. J. ;

Wolffs, Martin ;

Schenning, Albert P. H. J. ;

Sijbesma, Rint P. ;

Meijer, E. W. .

CHEMICAL REVIEWS, 2009, 109 (11) :5687-5754

[10] Metallosupramolecular approach toward functional coordination polymers [J].

Dobrawa, R ;

Würthner, F .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (21) :4981-4995

← 1 2 3 4 5 →